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I too generally choose leather gloves with a topcoat; however, I also choose function over form in such matters. I have a great pair of woolen gloves from Eddie Bauer that I often wear while engaged in amateur astronomy because of the warmth they provide. If it's cold enough and I'm going to be outside for very long I'll put those puppies on in a heartbeat without regard for the material.

Cruiser
Cruiser, no question that warmth is an important factor is selecting gloves, though I am curious why you would wear a dress topcoat when engaged in astronomy. In any event, I would suggest investing in a pair of glove liners, which I think you will find will substantially boost the insulating effect of leather gloves without impairing their appearance.
 
I coordinate my gloves and hat to the overcoat.
 
Cruiser, no question that warmth is an important factor is selecting gloves, though I am curious why you would wear a dress topcoat when engaged in astronomy. In any event, I would suggest investing in a pair of glove liners, which I think you will find will substantially boost the insulating effect of leather gloves without impairing their appearance.
I don't wear a topcoat while engaged in astronomy. What I said was that I have woolen gloves that I often wear while engaged in astronomy that I have also worn with a topcoat on a couple of occasions. I have cold weather gear that I wear for astronomy that is much warmer than a topcoat will ever be, more suited for the Arctic than the office. This includes the aforementioned glove liners.

In fact, in really cold weather when I'm out under the stars in the middle of the night I don't wear gloves at all but rather mittens. Not only are mittens much warmer than gloves but they can also be taken on and off more easily and quickly in the cold and dark. Since use of the fingers is so important when using small eyepieces and computer controls, some mittens have velcro secured pieces so that the fingers can be exposed briefly without removing the entire mitten. With glove liners on under the mittens one maintains the finger dexterity needed to push small buttons, etc. without exposing the skin.

Cruiser
 
While I swear by glove liners too, for this same reason, Cruiser (well, not telescopes anymore, but various other outdoor stuff where I need to occasionallty remove gloves/mittens but still want some coveragge), depending on controsl you're using, might be able to use a pair of shooting mittens to lessen your exposure even more. They split off not jsut the thumb, but the forefinger into seperate fingers, and then other three in regular mitten style. This gives you more dexterity, but still keeps warm (shootesr use them, with guns with big enough trigger guards, to shoot without removing but still have the extra warmth of mittens). Can find them very cheap at surplus stores, might be worth trying to see if they'd work for you.

Anwyay, back on topic. :) With a short coat I might coordinate with shoes, but with longer topcoat I'm more likely to choose gloves based on the color of the coat than the shoes. Esp as good chance I'm just wearing plain black rubber overshoes over some nice dress shoes, so by that rule, would always be wearing black rubber gloves to match the overshoes. :)
 
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